Free: Contests & Raffles.
Those look like scratches to me. Wad residue is usually in the forcing cone and the choke only.
Are they hand loads or factory loads?
Second question. God forbid they are scratches... Is that a problem? or nothing to worry about?
Try wrapping a piece of one of these around a brush and chuck the cleaning rod in a drill. Soak the pad in WD-40 and run it in the bore with drill on low speed.
Forget the bear spray, use wasp killer. Concentrated delivery stream, 10X the product, and only $3.00 on sale.