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I am a commercial fisherman, and wear Xtra-tuff rubber boots almost daily. I swear by Bama socks. I don't know what they are made of, but they are a blue bootie that wicks sweat away. I can go 6-10 hours on a pair depending on work load. When I crab fish in Alaska, it gets cold enough (-40) that the inside of my boots freeze, but, these bama socks are like a sweat check-valve.... I think they are made in Poland.... works great in.waders too
Nylons are good for a liner. The same kinds that women like to dress up in, except the sock style. That way you still fit in your broken in boots, too.